MARC details
| 000 -LEADER |
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| fixed length control field |
02584nam a2200301Ia 4500 |
| 003 - CONTROL NUMBER IDENTIFIER |
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| control field |
MX-MdCICY |
| 005 - DATE AND TIME OF LATEST TRANSACTION |
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| control field |
20250625162458.0 |
| 040 ## - CATALOGING SOURCE |
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| Transcribing agency |
CICY |
| 090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN) |
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| Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) |
B-20960 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
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| fixed length control field |
250602s9999 xx |||||s2 |||| ||und|d |
| 245 10 - TITLE STATEMENT |
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| Title |
Activity and selectivity of nickel-exchanged silica-alumina catalysts for the oligomerization of propene and 1-butene into distillate-range products |
| 490 0# - SERIES STATEMENT |
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| Volume/sequential designation |
Applied Catalysis A: General, 248(1-2), p.239-248, 2003 |
| 520 3# - SUMMARY, ETC. |
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| Summary, etc. |
The oligomerization of propene and 1-butene into C10+ or distillate-range products has been studied using Ni(II)-exchanged silica-alumina catalysts in a fixed-bed flow-reactor. The reaction temperature was varied between 40 and 350 °C, and pressures between 0.75 and 4.5 MPa were applied. As reported previously for the oligomerization of ethene, two temperature regions of high catalyst activity were also found with propene and 1-butene. At low temperature (±120 °C), mainly selective nickel-catalyzed oligomerization was observed, with the oligomers formed consisting of integral multiples of the monomer (true oligomerization). In this temperature region, the reactivity of the alkenes was found to decrease with increasing chain length (ethene?propene>1-butene). As the reaction temperature is raised, acid-catalyzed oligomerization contributes increasingly to the product spectrum, and this is evidenced by the formation of products composed of non-integral multiples of the monomer (hetero-oligomerization). The mass percentage of C10+ product which can be obtained in a straight run at low temperature (±120 °C), high pressure (3.5 MPa)and a MHSV=2 h?1, varied as follows: ?35 percent from ethene, ?25 percent from propene and ?10 percent from 1-butene. However, more than 50 percent distillate-range products can be obtained from 1-butene at temperatures >220 °C. Diesel fractions with satisfactory cetane numbers were obtained only from ethene as feedstock. Low reaction temperatures and high space velocities have a beneficial influence on the cetane number of the final product. |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
NICKEL |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
SILICA-ALUMINA |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
HETEROGENEOUS |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
OLIGOMERIZATION |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
ETHENE |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
PROPENE |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
1-BUTENE |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
DIESEL |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM |
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| Topical term or geographic name entry element |
CETANE NUMBER |
| 700 12 - ADDED ENTRY--PERSONAL NAME |
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| Personal name |
Heveling, J. |
| 700 12 - ADDED ENTRY--PERSONAL NAME |
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| Personal name |
Nicolaides, C. P. |
| 700 12 - ADDED ENTRY--PERSONAL NAME |
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| Personal name |
Scurrell, M. S. |
| 856 40 - ELECTRONIC LOCATION AND ACCESS |
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| Uniform Resource Identifier |
<a href="https://drive.google.com/file/d/1EE8odbMWweC7rxX6kgjOJZsVhXeJURuC/view?usp=drivesdk">https://drive.google.com/file/d/1EE8odbMWweC7rxX6kgjOJZsVhXeJURuC/view?usp=drivesdk</a> |
| Public note |
Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
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| Source of classification or shelving scheme |
Clasificación local |
| Koha item type |
Documentos solicitados |
