Sulfided NiMo/(Al)-MCM-41 Catalysts for Anisole Hydrodeoxygenation: Impact of Aluminium Incorporation in the Mesostructured Support (Record no. 55123)

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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625162500.0
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Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-21045
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245 10 - TITLE STATEMENT
Title Sulfided NiMo/(Al)-MCM-41 Catalysts for Anisole Hydrodeoxygenation: Impact of Aluminium Incorporation in the Mesostructured Support
490 0# - SERIES STATEMENT
Volume/sequential designation ChemistrySelect, 7(42), p.e202203979, 2022
520 3# - SUMMARY, ETC.
Summary, etc. NiMoS nanocatalysts supported on MCM-41 modified with aluminium were studied in the anisole hydrodeoxygenation. Our interest was to study the effect of the Al incorporation to the support on the activity and selectivity. The results indicate that the catalytic behaviour strongly depended on the Al presence in the MCM-41 support and its loading. The anisole conversions and the respective pseudo-first-order rate constants increased with Al-incorporation compared to the NiMo/Si-MCM-41 sample. The highest catalytic activity was obtained with the NiMo/Al-MCM-41(60)nanocatalyst. Aluminum presence in the support also had a strong effect on the selectivity of the catalysts, promoting the formation of phenol as an intermediate product mainly through demethylation of the O-CH3 group of anisole, as well as through demethylation of 2-methylphenol intermediate. These results were ascribed to an increased acidity of the Al-MCM-41-supported samples and the participation of these acidic sites in the interaction with anisole and oxygen-containing reaction intermediates.ANTIVIRALS percentCOVID-19 percentEBOLA
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Méndez, F. J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name González-Mota, M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Vargas-Villagrán, H.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name González-García, G.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Bokhimi, X.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Klimova, T. E.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/open?id=1UiaGBv1wVYkgFGkAoPwiZqTjyeOSa8Sz&usp=drive_copy">https://drive.google.com/open?id=1UiaGBv1wVYkgFGkAoPwiZqTjyeOSa8Sz&usp=drive_copy</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-21045 25.06.2025 25.06.2025 Documentos solicitados