Insight into the evolution of membrane chemical degradation in proton exchange membrane fuel cells:From theoretical analysis to model developing (Record no. 55300)

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fixed length control field 02349nam a2200265Ia 4500
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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625164351.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-21229
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245 10 - TITLE STATEMENT
Title Insight into the evolution of membrane chemical degradation in proton exchange membrane fuel cells:From theoretical analysis to model developing
490 0# - SERIES STATEMENT
Series statement Journal of Power Sources. 599, 234238, 2024, DOI: 10.1016/j.jpowsour.2024.234238
520 3# - SUMMARY, ETC.
Summary, etc. The chemical degradation of the proton exchange membrane (PEM) causes the changes in membrane properties and morphology, which directly affects the cell performance and membrane degradation. In this work, the changes of PEM during the chemical degradation are theoretically analyzed at both microscopic and mesoscopic levels. Based on the theoretical study, a bidirectionally coupled physical model of PEM fuel cell (PEMFC) performance and PEM chemical degradation is developed, which is used to investigate the evolutions of cell performance and chemical degradation. It can be found that the open circuit voltage first increases slightly and then decreases with time, and the ohmic loss increases rapidly under accelerated degradation conditions. The membrane chemical degradation is analyzed in terms of four aspects: the mass loss rate of the membrane, the region of pronounced degradation, the contribution of different degradation mechanisms and the proportion of ionomer species remaining. Furthermore, the effect of operating conditions on the degradation is examined. The degradation is most sensitive to voltage and has the fastest rate at high voltage, high temperature, high gas pressure and relative humidity of 60%. This work provides a deep insight into the PEM chemical degradation, which is instructive for the long-term prediction of PEMFC lifetime. © 2024 Elsevier B.V.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element BIDIRECTIONAL COUPLING MODEL
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CHEMICAL MEMBRANE DEGRADATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PEM CHANGES
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYMER ELECTROLYTE MEMBRANE FUEL CELL
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Chen S.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Hao M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Hu Y.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Liu K.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Li Y.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1UkTILYp0a7GyoYgNEjlXHpvOiqinibg9/view?usp=drivesdk">https://drive.google.com/file/d/1UkTILYp0a7GyoYgNEjlXHpvOiqinibg9/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta @cicy.edu.mx
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Source of classification or shelving scheme Clasificación local
Koha item type Documentos solicitados
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-21229 25.06.2025 25.06.2025 Documentos solicitados