Synthesis, characterization and properties of polyimides with spirobisbenzoxazole scaffold structure (Record no. 55452)

MARC details
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fixed length control field 01931nam a2200301Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625164354.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-21392
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245 10 - TITLE STATEMENT
Title Synthesis, characterization and properties of polyimides with spirobisbenzoxazole scaffold structure
490 0# - SERIES STATEMENT
Series statement Polymer. 254, 125091, 2022, DOI: 10.1016/j.polymer.2022.125091
520 3# - SUMMARY, ETC.
Summary, etc. Novel diamines containing spirobisbenzoxazole scaffold structure were successfully synthesized. These diamines were homopolymerized with commercial 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and cyclohexanedianhydride (H'PMDA) to prepare a series of benzoxazole based polyimides (PBOIs). The obtained PBOIs exhibited good organic solubility and outstanding thermal properties, including glass transition temperature (Tg) of 355-400 °C and 5% thermal decomposition temperatures (Td5%) of 474-490 °C. Meanwhile, these polymer films exhibited excellent mechanical strength, such as tensile strength of 79.4-92.1 MPa and elongation at break of 19.5%?31.2%. In addition, such PBOIs have been proved to be novel microporous polymer with pore width distribution of 5-7 Å and BET surface area of 281-378 m2/g. The permeability-selectivity relationship of H'PMDA based PBOIs was close to the 2008 Robeson upper bound for CO2/CH4 and O2/N2 gas pairs, showing promise in the field of gas separation. © 2022 Elsevier Ltd
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element GAS PERMEABILITY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYIMIDE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SOLUBLE
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Chen H.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Dai F.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Wang M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Ke Z.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Yan K.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Li D.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Chen C.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Qian G.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Yu Y.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1QRCEopNvYISSDEDfqYabVVpS1QwAyUVh/view?usp=drive_link">https://drive.google.com/file/d/1QRCEopNvYISSDEDfqYabVVpS1QwAyUVh/view?usp=drive_link</a>
Public note Para ver el documento ingresa a Google con tu cuenta @cicy.edu.mx
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Clasificación local
Koha item type Documentos solicitados
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-21392 25.06.2025 25.06.2025 Documentos solicitados