Laccase immobilized on chitosan-polyacrylic acid microspheres as highly efficient biocatalyst for naphthol green B and indigo carmine degradation (Record no. 55581)

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fixed length control field 02935nam a2200325Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250626080926.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-20217
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 250602s9999 xx |||||s2 |||| ||und|d
245 10 - TITLE STATEMENT
Title Laccase immobilized on chitosan-polyacrylic acid microspheres as highly efficient biocatalyst for naphthol green B and indigo carmine degradation
490 0# - SERIES STATEMENT
Series statement Chemical Engineering Journal, 329, p.135654, 2022
500 ## - GENERAL NOTE
General note Artículo
520 3# - SUMMARY, ETC.
Summary, etc. Low cost and non-toxic microspheres constituted by different ratios of chitosan (Cs) and polyacrylic acid (PAA) were manufactured as carriers for laccase (Lc). The CsPAA microspheres characterization proved that the PAA content played an important role on the size, surface morphology and rheological properties, and modulated the enzyme immobilization. The immobilization of Lc involved a multi-step procedure in which the 1-ethyl-3-(3- dimethylaminopropyl carbodiimide hydrochloride (EDC) was used as "zero length" crosslinker. The product with the largest active enzyme amount (44.38 mg Lc/g dry support), and the best operational stability profile was 10CsPAALc3. Also, this product contained the lowest PAA concentration and had excellent rheological properties. Moreover, two current hazardous chemicals, indigo carmine (IC) and naphthol green B (NG), were used as model dyes in practical applications. The biocatalytic decomposition of NG and IC was 1.67 and 2.4 times faster for 10CsPAALc3 compared to the free enzyme. The kinetic profile revealed that the immobilized Lc was less prone to substrate, operational and thermal inactivation. For example, the thermal inactivation for 10CsPAALc3 decreased by approximately 25 percent when dyes were used as substrate and by 11.71 percent for ABTS, as compared with the free Lc. The recycling test showed that in 5 cycles the immobilized Lc preserves 81 percent with NG and respectively 72 percent for IC of initial activity. The results prove that the new immobilized product can be successfully used in indigoid and metal-complex dyes biodegradation.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CHITOSAN-POLYACRYLIC ACID MICROSPHERE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element LACCASE FROM TRAMETES VERSICOLOR IMMOBILIZATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element "ZERO LENGTH" CROSSLINKER
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element KINETIC STUDY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element DYE DISCOLORATION
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Leontieș, A. R.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Răducan, A.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Culiță, D. C.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Alexandrescu, E.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Moroșan, A.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Mihaiescu, D. E.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Aricov, L.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/15_Yv6nrhiJu7IpHdedIevC1RjZWB9IsY/view?usp=drive_link">https://drive.google.com/file/d/15_Yv6nrhiJu7IpHdedIevC1RjZWB9IsY/view?usp=drive_link</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://docs.google.com/document/d/1JwrPq_9L9BWUcuvcMKQGG6ZD5M7R2Npi/edit?usp=drive_link&ouid=106479092411225478875&rtpof=true&sd=true">https://docs.google.com/document/d/1JwrPq_9L9BWUcuvcMKQGG6ZD5M7R2Npi/edit?usp=drive_link&ouid=106479092411225478875&rtpof=true&sd=true</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 26.06.2025   B-20217 26.06.2025 26.06.2025 Documentos solicitados