Heteroatom-containing degradable polymers by ring-opening metathesis polymerization (Record no. 55590)

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control field MX-MdCICY
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control field 20250626080926.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-20467
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Title Heteroatom-containing degradable polymers by ring-opening metathesis polymerization
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Series statement Progress in Polymer Science, 139, p.101656, 2023
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General note Artículo
520 3# - SUMMARY, ETC.
Summary, etc. The incorporation of heteroatom-containing weak bonds along polymer backbones has become a popular tool to accelerate degradation. Many methods have already been reported for the synthesis of degradable heteroatom-containing polymers based mainly on conventional step-growth polymerization and chain-growth ring-opening polymerization (ROP). In recent years, ring-opening metathesis polymer[1]ization (ROMP) has evolved as an emerging approach for the synthesis of various types of degradable polymers, from carbocyclic norbornene derivatives to heterocyclic olefin monomers. Classic ruthenium (Ru)-based catalysts exhibit not only high reactivity to C=C double bonds but also high tolerance to po[1]lar functional groups. Hence, a rich range of functional groups can be incorporated into cyclic olefin monomers and then transferred to the polymer backbones. This review covers the synthesis of the various heteroatom-containing degradable (co)polymers via ROMP, including poly(thio)acetals/polyketals, polyorthoesters, polyesters, polycarbonates, polyphosphoesters/polyphosphoamidates, poly(enol ether)s, poly(silyl ether)s, polydisulfides, polyketones, polyacylsilanes, polyamides, and polyureas, as well as their degradable mechanisms under different conditions. The review also highlights applications in tissue engineering and medicine.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element RING-OPENING METATHESIS POLYMERIZATION
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Topical term or geographic name entry element DEGRADABLE POLYMERS
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Topical term or geographic name entry element HYDROLYTIC DEGRADATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element HETEROCYCLIC OLEFIN
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Xu, J., & Hadjichristidis, N.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1IUknfSB58lPmTHlGAQiPACGtVcKv5Eq6/view?usp=drive_link">https://drive.google.com/file/d/1IUknfSB58lPmTHlGAQiPACGtVcKv5Eq6/view?usp=drive_link</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 26.06.2025   B-20467 26.06.2025 26.06.2025 Documentos solicitados