''Buckets effect" in the kinetics of electrocatalytic reactions (Record no. 55648)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 01995nam a2200253Ia 4500 |
| 003 - CONTROL NUMBER IDENTIFIER | |
| control field | MX-MdCICY |
| 005 - DATE AND TIME OF LATEST TRANSACTION | |
| control field | 20250626083335.0 |
| 040 ## - CATALOGING SOURCE | |
| Transcribing agency | CICY |
| 090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN) | |
| Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) | B-21579 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION | |
| fixed length control field | 250602s9999 xx |||||s2 |||| ||und|d |
| 245 10 - TITLE STATEMENT | |
| Title | ''Buckets effect" in the kinetics of electrocatalytic reactions |
| 490 0# - SERIES STATEMENT | |
| Series statement | Journal of Energy Chemistry, 89, p.388-396, 2024 |
| 500 ## - GENERAL NOTE | |
| General note | Artículo |
| 520 3# - SUMMARY, ETC. | |
| Summary, etc. | In this study, we systematically investigated the effect of proton concentration on the kinetics of the oxygen reduction reaction (ORR) on Pt(111) in acidic solutions. Experimental results demonstrate a rectangular hyperbolic relationship, i.e., the ORR current excluding the effect of other variables increases with proton concentration and then tends to a constant value. We consider that this is caused by the limitation of ORR kinetics by the trace oxygen concentration in the solution, which determines the upper limit of ORR kinetics. A model of effective concentration is further proposed for rectangular hyperbolic relationships: when the reactant concentration is high enough to reach a critical saturation concentration, the effective reactant concentration will become a constant value. This could be due to the limited concentration of a certain reactant for reactions involving more than one reactant or the limited number of active sites available on the catalyst. Our study provides new insights into the kinetics of electrocatalytic reactions, and it is important for the proper evaluation of catalyst activity and the study of structureperformance relationships. |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name entry element | OXYGEN REDUCTION REACTION |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name entry element | KINETICS |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name entry element | ZERO ORDER |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name entry element | RECTANGULAR HYPERBOLIC RELATIONSHIP |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name entry element | PH EFFECT |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Cui, H. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Chen, Y. X. |
| 856 40 - ELECTRONIC LOCATION AND ACCESS | |
| Uniform Resource Identifier | <a href="https://drive.google.com/file/d/1w333neHl5VtKpxMZU7EutOEKlGq9wq3W/view?usp=drive_link">https://drive.google.com/file/d/1w333neHl5VtKpxMZU7EutOEKlGq9wq3W/view?usp=drive_link</a> |
| Public note | Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Source of classification or shelving scheme | Clasificación local |
| Koha item type | Documentos solicitados |
| Lost status | Source of classification or shelving scheme | Damaged status | Not for loan | Collection | Home library | Current library | Shelving location | Date acquired | Total checkouts | Full call number | Date last seen | Price effective from | Koha item type |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Clasificación local | Ref1 | CICY | CICY | Documento préstamo interbibliotecario | 26.06.2025 | B-21579 | 26.06.2025 | 26.06.2025 | Documentos solicitados |