Optimization of electrochemical hydrogen compression through computational modeling (Record no. 55737)

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fixed length control field 02766nam a2200277Ia 4500
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control field MX-MdCICY
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control field 20250626090915.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-21672
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Title Optimization of electrochemical hydrogen compression through computational modeling
490 0# - SERIES STATEMENT
Series statement International Journal of Hydrogen Energy, 47(78), p.33195-33208, 2022
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General note Artículo
520 3# - SUMMARY, ETC.
Summary, etc. One of the main challenges in developing the hydrogen infrastructure is the distribution and storage of hydrogen. A common method to store hydrogen is as a compressed gas. Electrochemical compression (ECC) is a promising technology that can overcome some of the disadvantages of conventional mechanical compressors. ECC employs an externally powered electrochemical cell containing a polymer electrolyte membrane to compress the gas. This work presents a comprehensive 3D ECC model developed for a single cell using COMSOL Multiphysics 5.6 that incorporates all relevant physical and electrochemical processes, and examines the effect of key parameters on ECC performance. It also considers the important phenomenon of back diffusion resulting from the high-pressure differential between the cathode and anode during compression. Results from the current simulations were validated against experimental results obtained previously in our lab. Simulations were first conducted for the unpressurized cathode to understand the effect of membrane thickness, relative humidity of the anode hydrogen supply, temperature, and gas diffusion layer thickness on ECC performance. Next, simulations were conducted for the pressurized cathode, with and without considering back diffusion. In the absence of back diffusion, the pressure ratio reaches the value predicted by the Nernst equation. However, the presence of back diffusion greatly reduces the pressure ratio as was also observed in experiments. The study reveals that three parameters in particular viz. Membrane thickness, operating temperature, and voltage must be carefully selected to optimize ECC operation. These results also suggest that ECC is a viable alternative to conventional technologies for hydrogen compression. This work also provides a foundation for the modeling and analysis of full-scale ECC systems.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element HYDROGEN
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ELECTROCHEMICAL COMPRESSOR
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ELECTROLYZER
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element FUEL CELL
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element BACK DIFFUSION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element OPTIMIZATION
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Aziz, M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Aryal, U. R.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Prasad, A. K.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1oAkJgONL8y51V82bQsRM--GvGK44idoV/view?usp=drive_link">https://drive.google.com/file/d/1oAkJgONL8y51V82bQsRM--GvGK44idoV/view?usp=drive_link</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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Source of classification or shelving scheme Clasificación local
Koha item type Documentos solicitados
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 26.06.2025   B-21672 26.06.2025 26.06.2025 Documentos solicitados