Beta-phenoxyethyl alky (aryl)Ketones, rearrangement and conversion into benzopyrylium salts

Tipo de material: Texto

TextoSeries ; Tetrahedron, 28(16), p.4449-4453, 1972Trabajos contenidos:

Chatterjea, J.N
Prassad, R
Jha, H. C

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Resumen: The rearrangement of some -phenoxyethyl alkyl(aryl)ketones to 4-hydroxyphenoxyethyl alkyl(aryl)ketones has been studied. The latter undergo rearrangement under oxidative conditions to flavilium salts such as 0-trimethylapigeninidin chloride or 0-tetramethylluteolinidui chloride. The mechanism of these changes has been discussed.

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The rearrangement of some -phenoxyethyl alkyl(aryl)ketones to 4-hydroxyphenoxyethyl alkyl(aryl)ketones has been studied. The latter undergo rearrangement under oxidative conditions to flavilium salts such as 0-trimethylapigeninidin chloride or 0-tetramethylluteolinidui chloride. The mechanism of these changes has been discussed.

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