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Candida antartica Lipase B Catalyzed Polycaprolactone Synthesis: Effects of Organic Media and Temperature

Tipo de material: TextoTextoSeries ; BioMacromolecules, 1, p.133-138, 2000Trabajos contenidos:
  • Kumar, A
  • Gross, R.A
Recursos en línea: Resumen: Engineering of the reaction medium and study of an expanded range of reaction temperatures were carried out in an effort to positively influence the outcome of Novozyme-435 (immobilized Lipase B from Candida antarctica)catalyzed ¤-CL polymerizations. A series of solvents including acetonitrile, dioxane, tetrahydrofuran, chloroform, butyl ether, isopropyl ether, isooctane, and toluene (log P from -1.1 to 4.5)were evaluated at 70 ïC. Statistically (ANOVA), two significant regions were observed. Solvents having log P values from -1.1 to 0.49 showed low propagation rates (e30
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Documentos solicitados Documentos solicitados CICY Documento préstamo interbibliotecario Ref1 B-11033 (Browse shelf(Opens below)) Available

Engineering of the reaction medium and study of an expanded range of reaction temperatures were carried out in an effort to positively influence the outcome of Novozyme-435 (immobilized Lipase B from Candida antarctica)catalyzed ¤-CL polymerizations. A series of solvents including acetonitrile, dioxane, tetrahydrofuran, chloroform, butyl ether, isopropyl ether, isooctane, and toluene (log P from -1.1 to 4.5)were evaluated at 70 ïC. Statistically (ANOVA), two significant regions were observed. Solvents having log P values from -1.1 to 0.49 showed low propagation rates (e30

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