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Solventless Enantioelective Ring-Opening Polymerization of Substituted ¤-Caprolactones by Enzymatic Catalysis

Tipo de material: TextoTextoSeries ; Macromolecules, 35(9), p.3380-3386, 2002Trabajos contenidos:
  • Al-Azemi, T.F
  • Kondaveti, L
  • Bisht, K.S
Recursos en línea: Resumen: Highly (S)-enriched substituted poly(¤-caprolactone)s were synthesized from 4-methyl-¤- caprolactone (4-MeCL)and 4-ethyl-¤-caprolactone (4-EtCL)by lipase Novozym-435 (from Candida antarctica)catalyzed ring-opening polymerizations. The polymerizations were performed in bulk, thus eliminating the need for solvents in the polymerization process. Poly(4-EtCL)and poly(4-MeCL)having >95
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Highly (S)-enriched substituted poly(¤-caprolactone)s were synthesized from 4-methyl-¤- caprolactone (4-MeCL)and 4-ethyl-¤-caprolactone (4-EtCL)by lipase Novozym-435 (from Candida antarctica)catalyzed ring-opening polymerizations. The polymerizations were performed in bulk, thus eliminating the need for solvents in the polymerization process. Poly(4-EtCL)and poly(4-MeCL)having >95

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