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Efficient Ring-Opening Polymerization and Copolymerization of ¤-Caprolactone and ö-Pentadecalactone Catalyzed by Candida antartica Lipase B

Tipo de material: TextoTextoSeries ; Macromolecules, 33(17), p.6303-6309, 2000Trabajos contenidos:
  • Kumar, A
  • Kalra, B
  • Dekhterman, A
  • Gross, R.A
Recursos en línea: Resumen: In this paper, Novozyme-435-catalyzed ö-pentadecalactone and ö-pentadecalactone/¤- caprolactone polymerizations were investigated. Novozyme-435-catalyzed ö-pentadecalactone polymerizations were studied in bulk and at ö-pentadecalactone-to-toluene ratios from 1:1 to 1:10 (wt/vol). By carrying out polymerizations with ö-pentadecalactone to toluene 1:1 wt/vol instead of in bulk, the monomer conversion (32 to 90
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In this paper, Novozyme-435-catalyzed ö-pentadecalactone and ö-pentadecalactone/¤- caprolactone polymerizations were investigated. Novozyme-435-catalyzed ö-pentadecalactone polymerizations were studied in bulk and at ö-pentadecalactone-to-toluene ratios from 1:1 to 1:10 (wt/vol). By carrying out polymerizations with ö-pentadecalactone to toluene 1:1 wt/vol instead of in bulk, the monomer conversion (32 to 90

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