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Electrocatalytic oxidation of NADH at mediator-modified electrode surfaces

Tipo de material: TextoTextoSeries ; Journal of Biotechnology, 27(2), p.129-142, 1993Trabajos contenidos:
  • Schuhmann, W
  • Huber, J
  • Wohlschlager, H
  • Strehlitz, B
  • Griindig, B
Tema(s): Recursos en línea: Resumen: The electrocatalytic oxidation of NADH at suitable electrode surfaces is of fundamental interest for the development of dehydrogenase-based enzyme electrodes. Copolymers of 3-(N-pyrrolo)-2,5,6-trichloro-l,4-benzoquinone or higher pyrrole-substituted chloranil derivatives with pyrrole and graphite/mediator electrodes with insolubilized phenazine and phenoxazine salts are investigated with respect to their electrocatalytic properties for the oxidation of NADH, their long-term operation stability, and the application in flow-injection systems with enzyme columns or in enzyme electrodes with immobilized dehydrogenases.
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The electrocatalytic oxidation of NADH at suitable electrode surfaces is of fundamental interest for the development of dehydrogenase-based enzyme electrodes. Copolymers of 3-(N-pyrrolo)-2,5,6-trichloro-l,4-benzoquinone or higher pyrrole-substituted chloranil derivatives with pyrrole and graphite/mediator electrodes with insolubilized phenazine and phenoxazine salts are investigated with respect to their electrocatalytic properties for the oxidation of NADH, their long-term operation stability, and the application in flow-injection systems with enzyme columns or in enzyme electrodes with immobilized dehydrogenases.

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