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Characterization of thermoplastic interpenetrating polymer networks by various thermal analysis techniques

Tipo de material: TextoTextoSeries ; Thermochimica Acta, 371(1-2), p.87-93, 2010Trabajos contenidos:
  • Vatalis, A.S
  • Delides, C.G
  • Georgoussis, G
  • Kyritsis, A
  • Grigorieva, O.P
  • Sergeeva, L.M
  • Brovko, A.A
  • Brovko, A.A
  • Shtompel, A.A
  • Neagu, E
  • Pissis, P
Tema(s): Recursos en línea: Resumen: Thermoplastic interpenetrating polymer networks (t-IPNs), prepared by melting and pressing of crystallizable polyurethane (CPU)and styrene/acrylic acid random copolymer (S/AA)in wide ranges of composition, were investigated by the combination of various thermal analysis techniques: differential scanning calorimetry (DSC), thermomechanical analysis (TMA), thermally stimulated depolarization currents (TSDC)and thermally stimulated conductivity (TSC)measurements, as well as broadband dielectric relaxation spectroscopy (DRS). The results show that the t-IPNs under investigation are microheterogeneous systems with contributions to microheterogeneity from both the heterogeneity of the individual polymers and the thermodynamic incompatibility of the components.
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Thermoplastic interpenetrating polymer networks (t-IPNs), prepared by melting and pressing of crystallizable polyurethane (CPU)and styrene/acrylic acid random copolymer (S/AA)in wide ranges of composition, were investigated by the combination of various thermal analysis techniques: differential scanning calorimetry (DSC), thermomechanical analysis (TMA), thermally stimulated depolarization currents (TSDC)and thermally stimulated conductivity (TSC)measurements, as well as broadband dielectric relaxation spectroscopy (DRS). The results show that the t-IPNs under investigation are microheterogeneous systems with contributions to microheterogeneity from both the heterogeneity of the individual polymers and the thermodynamic incompatibility of the components.

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