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Average dipole moments of aromatic polymer chains

Tipo de material: TextoTextoSeries ; High Performance Polymers, 8(3), p.427-431, 1996Trabajos contenidos:
  • Hinkley, J.A
Tema(s): Recursos en línea: Resumen: Recently, certain aromatic polyimides with polar substituents were shown to exhibit piezoelectricity after poling. To help interpret these results, mean square chain dipole moments for model chains were calulated using a rotational isomeric state scheme. Average moments ranged from 1.7 to 3.6 debye2 per backbone link, and correlated well with the magnitudes of the piezoelectric coefficients within the series.
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Recently, certain aromatic polyimides with polar substituents were shown to exhibit piezoelectricity after poling. To help interpret these results, mean square chain dipole moments for model chains were calulated using a rotational isomeric state scheme. Average moments ranged from 1.7 to 3.6 debye2 per backbone link, and correlated well with the magnitudes of the piezoelectric coefficients within the series.

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