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Motion in polyethylene. I. Temperature and crystallinity dependence of the specific heat.

Tipo de material: TextoTextoSeries ; The Journal of Chemical Physics, p.1203-1207, 1962Trabajos contenidos:
  • Wunderlich, B
Recursos en línea: Resumen: Data for the specific heat of polyethylene as a function of crystallinity are collected from 1° to 420°K. Specific heats, entropies, and enthalpies of the completely amorphous and crystalline polyethylene are extrapolated. The glass transition is located for the amorphous at 237°K with a ?Cp of 2.1 cal deg-1 (mole CH2)-1. Specific?heat values at constant volume are calculated for the crystalline polyethylene.
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Data for the specific heat of polyethylene as a function of crystallinity are collected from 1° to 420°K. Specific heats, entropies, and enthalpies of the completely amorphous and crystalline polyethylene are extrapolated. The glass transition is located for the amorphous at 237°K with a ?Cp of 2.1 cal deg-1 (mole CH2)-1. Specific?heat values at constant volume are calculated for the crystalline polyethylene.

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