Pheromone Synthesis, CXLV. Synthesis of the Enantiomers of Rhynchophorol [(E)-6-Methyl-2-hepten-4-ol], the Male-Produced Aggregation Pheromone of the American Palm Weevil, Rhynchophorus palmarum
Tipo de material:
TextoSeries ; Liebigs Annalen der Chemie, 1992(11), p.1195-1198, 1992Trabajos contenidos: - Mori, K
- Ishigami, K
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Both the enantiomers of rhynchophorol [(E)-6-methyl-2-hepten-4-ol (1)], the male-produced aggregation pheromone of the American palm weevil (Rhynchophorus palmarum), have been synthesized by reducing their precursors, (R)- and (S)-6-methyl-2-heptyn-4-ol (2), which have been prepared by lipasemediated asymmetric hydrolysis of the corresponding acetate and propionate.
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