Investigation of holocellulose-lignin interactions during pyrolysis of wood meal by TGA-FTIR.

Tipo de material: Texto

TextoSeries Biomass Conversion and Biorefinery, 13(5), 3731-3740, 2023Trabajos contenidos:

Yang, W
Yang, F
Zhang, X
Zhu, P
Peng, H
Chen, Z
Wu, S

Tema(s):

Recursos en línea:

Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx

Resumen: Pyrolysis of wood meal, a holocellulose-lignin mixture, holocellulose, and lignin was carried out using TGA-FTIR to investigate the effects of holocellulose-lignin interactions on the pyrolysis behavior of wood meal, in this study. The interactions between holocellulose and lignin showed no obvious effects on the pyrolysis behavior of holocellulose in wood meal at temperatures under 325 °C. However, the interactions did inhibit the pyrolysis of both lignin and holocellulose at higher temperatures, probably because of the high energy needed to dissociate the covalent linkages between holocellulose and lignin. Only a portion of covalent linkages were cracked at the temperatures of 215-395 °C, whereas they could be just barely destroyed at 395-565 °C. The char generated from holocellulose that was connected with lignin by unabridged covalent linkages would inhibit the decomposition of lignin at high pyrolysis temperatures by adsorbing on its surface, resulting in a higher char residue yield compared to that of the holocellulose-lignin mixture after pyrolysis.

Tags from this library: No tags from this library for this title. Log in to add tags.

Average rating: 0.0 (0 votes)

Holdings
Item type	Current library	Collection	Call number	Status	Date due	Barcode
Documentos solicitados	CICY Documento préstamo interbibliotecario	Ref1	B-21926 (Browse shelf(Opens below))	Available

Browsing CICY shelves, Shelving location: Documento préstamo interbibliotecario, Collection: Ref1 Close shelf browser (Hides shelf browser)

Previous	No cover image available	No cover image available	No cover image available	No cover image available	No cover image available	No cover image available	No cover image available	Next
Previous	B-21923 The evolution of plants.	B-21924 Extreme physiology: Biomass and transcriptional profiling of three abandoned Agave cultivars.	B-21925 Investigating the Pyrolysis Properties of Cellulose and Lignin Isolated from Different Turkish Biomass Using TG-FTIR.	B-21926 Investigation of holocellulose-lignin interactions during pyrolysis of wood meal by TGA-FTIR.	B-21927 Amide-functionalized g-C3N4 nanosheet for the adsorption of arsenite (As3+): process optimization, experimental, and density functional theory insight.	B-21928 Deep eutectic solvent-modified polyvinyl alcohol/chitosan thin film membrane for dye adsorption: Machine learning modeling, experimental, and density functional theory calculations.	B-21929 Live long and prosper: acetate and its effects on longevity in batch culturing of Chlamydomonas reinhardtii.	Next

Artículo

Pyrolysis of wood meal, a holocellulose-lignin mixture, holocellulose, and lignin was carried out using TGA-FTIR to investigate the effects of holocellulose-lignin interactions on the pyrolysis behavior of wood meal, in this study. The interactions between holocellulose and lignin showed no obvious effects on the pyrolysis behavior of holocellulose in wood meal at temperatures under 325 °C. However, the interactions did inhibit the pyrolysis of both lignin and holocellulose at higher temperatures, probably because of the high energy needed to dissociate the covalent linkages between holocellulose and lignin. Only a portion of covalent linkages were cracked at the temperatures of 215-395 °C, whereas they could be just barely destroyed at 395-565 °C. The char generated from holocellulose that was connected with lignin by unabridged covalent linkages would inhibit the decomposition of lignin at high pyrolysis temperatures by adsorbing on its surface, resulting in a higher char residue yield compared to that of the holocellulose-lignin mixture after pyrolysis.

There are no comments on this title.

to post a comment.