TY  - BOOK
AU  - Lubner Ce
AU  - Knorzer P.
AU  - Silva Pj
AU  - Vincent Ka
AU  - Happe T
AU  - Bryant Da
AU  - Golbeck Jh
TI  - Wiring an [FeFe]-Hydrogenase with Photosystem I for Light-Induced Hydrogen Production
N2  - A molecular wire is used to connect two proteins through their physiologically relevant redox cofactors to facilitate direct electron transfer. Photosystem I (PS I)and an [FeFe]-hydrogenase (H2ase)serve as the test bed for this new technology. By tethering a photosensitizer with a hydrogen-evolving catalyst, attached by Fe-S coordination bonds between the FB iron-sulfur cluster of PS I and the distal iron-sulfur cluster of H2ase, we assayed electron transfer between the two components via light-induced hydrogen generation. These hydrogen-producing nanoconstructs self-assemble when the PS I variant, the H2ase variant, and the molecular wire are combined
UR  - https://drive.google.com/file/d/1hiV_0UeEiEJ4ULzRGhoPbAzh22wqYCWS/view?usp=drivesdk
ER  -