TY - BOOK AU - Sterner,O. AU - Etzel,W. AU - Mayer,A. AU - Anke,H. TI - Omphalotin, A New Cyclic Peptide with Potent Nematicidal Activity from Omphalotus Olearius II. Isolation and Structure Determination KW - OMPHALOTUS OLEARIUS KW - OMPHALOTIN KW - CYCLOPEPTIDE KW - STRUCTURE DETERMINATION N2 - The structure of the potent nematicide omphalotin, isolated from the mycelia of the basidiomycete Omphalotus olearius, was determined by spectroscopic techniques. Omphalotin is a cyclic dodecapeptide consisting of 3 glycine, 5 valine, 3 isoleucine and 1 tryptophane, and 9 of the 12 a-nitrogens are methylated. HMBC and NOESY correlations between the N-methyl groups and the a-carbonda-hydrogens established the sequence of amino acids UR - https://drive.google.com/file/d/1EqU6fswod8fbHZZ6HybdmfY7efbKFcv4/view?usp=drivesdk ER -