TY - BOOK AU - Chen,Z. AU - Ren,W. AU - Gao,L. AU - Liu,B. AU - Pei,S. AU - Cheng,H.-M. TI - Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition KW - CHEMICAL VAPOUR DEPOSITION KW - DIRECT SYNTHESIS KW - ELECTRICAL AND MECHANICAL PROPERTIES KW - ELECTRICAL CONDUCTIVITY KW - FAST TRANSPORT CHANNELS KW - FLEXIBLE NETWORKS KW - GRAPHENE SHEETS KW - HIGH ELECTRICAL CONDUCTIVITY KW - JUNCTION CONTACT RESISTANCE KW - LOW QUALITIES KW - MACROSCOPIC STRUCTURE KW - MACROSTRUCTURES KW - NETWORK STRUCTURES KW - ORDERS OF MAGNITUDE N2 - Integration of individual two-dimensional graphene sheets into macroscopic structures is essential for the application of graphene. A series of graphene-based composites and macroscopic structures have been recently fabricated using chemically derived graphene sheets. However, these composites and structures suffer from poor electrical conductivity because of the low quality and/or high inter-sheet junction contact resistance of the chemically derived graphene sheets. Here we report the direct synthesis of three-dimensional foam-like graphene macrostructures, which we call graphene foams (GFs), by template-directed chemical vapour deposition. A GF consists of an interconnected flexible network of graphene as the fast transport channel of charge carriers for high electrical conductivity. Even with a GF loading as low as ? 0.5 wt per cent, GF/poly(dimethyl siloxane)composites show a very high electrical conductivity of ?10 S cm-1, which is ?6 orders of magnitude higher than chemically derived graphene-based composites. Using this unique network structure and the outstanding electrical and mechanical properties of GFs, as an example, we demonstrate the great potential of GF/poly(dimethyl siloxane)composites for flexible, foldable and stretchable conductors. © 2011 Macmillan Publishers Limited. All rights reserved UR - https://drive.google.com/file/d/1e_C_eNKWRjmcYJocIlbbhdHOkiK43ds7/view?usp=drivesdk ER -