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Intramolecular Diels-Alder Reaction of 8-Trifluoromethyl-1, 3, 8-Nona-Trienes: An Access to Angular Trifluoromethylated Hydrindenes

Tipo de material: TextoTextoSeries ; Bulletin des Sociétés Chimiques Belges, 103(5-6), p.263-271, 1994Trabajos contenidos:
  • Zhu, G. D
  • Lancker, B. V
  • Haver, D. V
  • De Clercq, P. J
Recursos en línea: Resumen: The intramolecular Diels-Alder reaction of 8-trifluoromethyl-1,3,8-nonatrienes as a possible route toward angular trifluoromethylated hydrindenes is explored for the first time. As in the case of the parent 3-methyl nonatrienes, the cycloaddition was found to give predominantly trans-fused adducts.
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The intramolecular Diels-Alder reaction of 8-trifluoromethyl-1,3,8-nonatrienes as a possible route toward angular trifluoromethylated hydrindenes is explored for the first time. As in the case of the parent 3-methyl nonatrienes, the cycloaddition was found to give predominantly trans-fused adducts.

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