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Investigation of Factors Influencing the Chemoenzymatic Synthesis of Block Copolymers

Tipo de material: TextoTextoSeries ; Macromolecules, 38, p.4220-4225, 2005Trabajos contenidos:
  • De Geus, M
  • Peeters, J
  • Wolffs, M
  • Hermans, T
  • Palmans, A.R.A
  • Koning, C.E
  • Heise, A
Recursos en línea: Resumen: The chemoenzymatic synthesis of block copolymers from a bifunctional initiator using enzymatic ring-opening polymerization (eROP)and ATRP in two consecutive steps was investigated. First, a polycaprolactone (PCL)macroinitiator was obtained via an enzymatic ring-opening polymerization initiated by the bifunctional initiator. By carefully managing the water activity in the system, the amount of PCL not initiated by the bifunctional initiator was reduced to <5
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Documentos solicitados Documentos solicitados CICY Documento préstamo interbibliotecario Ref1 B-12825 (Browse shelf(Opens below)) Available

The chemoenzymatic synthesis of block copolymers from a bifunctional initiator using enzymatic ring-opening polymerization (eROP)and ATRP in two consecutive steps was investigated. First, a polycaprolactone (PCL)macroinitiator was obtained via an enzymatic ring-opening polymerization initiated by the bifunctional initiator. By carefully managing the water activity in the system, the amount of PCL not initiated by the bifunctional initiator was reduced to <5

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