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Trinorcassane and cassane diterpenoids from the seeds of Caesalpinia minax.

Tipo de material: TextoTextoSeries ; Fitoterapia, 102, p.177-181, 2015Trabajos contenidos:
  • Zheng, Y
  • Zhang, S. W
  • Xuan, L. J
Tema(s): Recursos en línea: Resumen: An unprecedented trinorcassane diterpenoid and a cassane furanoditerpenoid were isolated from the seeds of Caesalpinia minax. It is the first example of dicylic cassane-type trinorditerpenoid, which is different from reported 16- or 17-norcassane diterpenoids. The structure of the compounds was elucidated on the basis of 1D and 2D NMR analysis. Biosynthesis pathways are postulated, and this pathway was supported by semi-synthesis.
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Documentos solicitados Documentos solicitados CICY Documento préstamo interbibliotecario Ref1 B-18303 (Browse shelf(Opens below)) Available

An unprecedented trinorcassane diterpenoid and a cassane furanoditerpenoid were isolated from the seeds of Caesalpinia minax. It is the first example of dicylic cassane-type trinorditerpenoid, which is different from reported 16- or 17-norcassane diterpenoids. The structure of the compounds was elucidated on the basis of 1D and 2D NMR analysis. Biosynthesis pathways are postulated, and this pathway was supported by semi-synthesis.

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