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245 1 0 _aInnovative plasticized alginate obtained by thermo-mechanical mixing: Effect of different biobased polyols systems.
490 0 _vCarbohydrate Polymers, 157, p.669-676, 2017
520 3 _aPlasticized alginate films with different biobased polyols (glycerol and sorbitol)and their mixtures were successfully prepared by thermo-mechanical mixing instead of the usual casting-evaporation procedure. The microstructure and properties of the different plasticized alginate formulations were investigated by SEM, FTIR, XRD, DMTA and uniaxial tensile tests. SEM and XRD results showed that native alginate particles were largely destructured with the plasticizers (polyols and water), under a thermo-mechanical input. With increasing amount of plasticizers, the samples showed enhanced homogeneity while their thermal and mechanical properties decreased. Compared to sorbitol, glycerol resulted in alginate films with a higher flexibility due to its better plasticization efficiency resulting from its smaller size and higher hydrophilic character. Glycerol and sorbitol mixtures seemed to be an optimum to obtain the best properties. This work showed that thermo-mechanical mixing is a promising method to produce, at large scale, plasticized alginate-based films with improved properties.
650 1 4 _aALGINATE
650 1 4 _aGLYCEROL
650 1 4 _aPLASTICIZATION
650 1 4 _aSORBITOL
650 1 4 _aTHERMO-MECHANICAL MIXING
700 1 2 _aGao, C.
700 1 2 _aPollet, E.
700 1 2 _aAvérous, L.
856 4 0 _uhttps://drive.google.com/file/d/1AbgOEPnJpTvr45dIdkcWVWr4aT_FFgzm/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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