000 01286nam a2200241Ia 4500
003 MX-MdCICY
005 20250625124707.0
040 _cCICY
090 _aB-7759
245 1 0 _aImpedance study of methanol oxidation on platinum electrodes
490 0 _vElectrochimica Acta, 51(18), p.3827-3840, 2006
520 3 _aMethanol oxidation on Pt electrodes is studied by ac voltammetry. Data from voltammograms at frequencies from 0.5 Hz to 20 kHz are assembled into electrochemical impedance spectra and analysed using equivalent circuits. Inductive behavior and negative relaxation times are attributed to nucleation and growth behavior. The rate-determining step is proposed to be the reaction of adsorbed CO and OH at the edge of islands of OH, with competition between OH and CO adsorption for the released reaction sites.
650 1 4 _aIMPEDANCE
650 1 4 _aMETHANOL OXIDATION
650 1 4 _aPLATINUM AC VOLTAMMETRY
650 1 4 _aNUCLEATION AND GROWTH
700 1 2 _aSeland, F.
700 1 2 _aTunold, R.
700 1 2 _aHarrington, D.A.
856 4 0 _uhttps://drive.google.com/file/d/1K484fIkD4TOXpnSy8ZOWRkG-Mra4A3f5/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942 _2Loc
_cREF1
008 250602s9999 xx |||||s2 |||| ||und|d
999 _c42081
_d42081