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245 1 0 _aSynthesis of polymer-montmorillonite nanocomposites by in situ intercalative polymerization
490 0 _vNanotechnology, 13, p.549-553, 2002
520 3 _aTwo polymer-montmorillonite (MMT)nanocomposites have been synthesized by in situ intercalative polymerization. The styrene monomer is intercalated into the interlayer space of organically modified MMT, a layered clay mineral. Upon the intercalation, the complex is subsequently polymerized in the confinement environment of the interlayer space with a free radical initiator, 2,2-azobis isobutyronitrile. The aniline monomer is also intercalated and then polymerized within the interlayer space of sodium- and copper-MMT initiated by ammonium peroxodisulphate and interlayer copper cations respectively. X-ray diffraction indicates that the MMT layers are completely dispersed in the polystyrene matrix and an exfoliated structure has been obtained. The resulting polyaniline-MMT nanocomposites show a highly ordered structure of a single polyaniline layer stacked with the MMT layers. Fourier transform infrared spectra further confirm the intercalation and formation of both polymer-MMT nanocomposites.
700 1 2 _aZeng, Q.H.
700 1 2 _aWang, D.Z.
700 1 2 _aYu, A.B.
700 1 2 _aLu, G.Q.
856 4 0 _uhttps://drive.google.com/file/d/1RpIgMX9FXp7ihoaUsAWS95cIETYTiO1W/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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