000 01780nam a2200277Ia 4500
003 MX-MdCICY
005 20250625124727.0
040 _cCICY
090 _aB-8798
245 1 0 _aFluorene-containing sulfonated poly(arylene ether 1,3,4-oxadiazole)as proton-exchange membrane for PEM fuel cell application
490 0 _vJournal of Membrane Science, 291(1-2), p.140-147, 2007
520 3 _aFluorene-containing polymers were synthesized followed by sulfonation into a series of fluorene-containing sulfonated poly(arylene ether oxadiazole)s (SPAEO)using chlorosulfonic acid. The sulfonic acid groups can be controlled to be only attached onto the fluorenyl rings by optimizing the reaction conditions. Their properties of ionic exchange capacity, sulfonation degree, water-uptake, mechanical property, thermal and oxidative stabilities as well as proton conductivity of the synthesized SPAEO membranes were fully investigated. It was found that the synthesized SPAEO with the sulfonic acid groups on fluorenyl rings exhibited superior oxidative stability and highly proton conductivity when compared with other reported sulfonated poly(arylene ether)s. Therefore, they showed potential alternatives as the proton-exchange membrane for fuel cell application.
650 1 4 _aPOLYAROMATICS
650 1 4 _aSULFONATION
650 1 4 _aOXIDATIVE STABILITY
650 1 4 _aMEMBRANE
650 1 4 _aPROTON CONDUCTIVITY
700 1 2 _aShang, X.Y.
700 1 2 _aShuc, D.
700 1 2 _aWang, S.J.
700 1 2 _aXiao, M.
700 1 2 _aMenga, Y.Z.
856 4 0 _uhttps://drive.google.com/file/d/1_NOx_QxgoMxkE4UxX9sxocFkdxT3eXmG/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942 _2Loc
_cREF1
008 250602s9999 xx |||||s2 |||| ||und|d
999 _c43099
_d43099