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245	1	0	_aThe mechanism of vinyl interchange by nuclear magnetic resonance spectroscopy
490	0		_vTetrahedron, 22(9), p.3163-3171, 1966
520	3		_amechanism of the vinyl interchange reaction between benzoic acid and vinyl acetate and catalysed by mercury-II acetate and an acetic solution of the BF,-AcOH complex has been investigated by NMR spectroscopy. For this p"pose a/Q?'-trideutero-vinyl acetate and deutero-Oacetic acid have been synthesized. During the course of the vinyl interchange, the vinyl group is transferred as a whole entity from one carboxylate radical to the other without any carbon-hydrogen bond scission. /?-Acetoxy mercuri ethane aa'-diesters postulated aa intermediates of the reaction have been prepared and characterized; these compounds are effectively reaction intermediates. The isolation and structural elucidation of some deuterated ethylidene diestm demonstrates the mechanism of side reactions of the addition of acid to vinyl esters.
700	1	2	_aSLINCKX, G.
700	1	2	_aSMETS, G.
856	4	0	_uhttps://drive.google.com/file/d/1w1lwF6AHlN2SrtqUm4CGHXdD6YdG2frw/view?usp=drivesdk _zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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