000 01255nam a2200205Ia 4500
003 MX-MdCICY
005 20250625140621.0
040 _cCICY
090 _aB-9897
245 1 0 _aSolution phase studies towards the synthesis of triarylamine oligomers using a germanium linker on a solid support
490 0 _vTetrahedron Letters, 46(39):6717-6721, 2005
520 3 _aIn this letter, we describe the iterative solution phase synthesis of a triarylamine trimer as proof of concept towards the synthesis of oligomeric materials by solid-phase synthesis. Our model system utilises the stability of germanium linkers to nucleophilic conditions to develop efficient steps towards oligomer synthesis via (i)selective deprotection of tert-butyl-dimethyl-silyl ether (OTBDMS)functionality, (ii)conversion to reactive trifluoromethanesulfonate (triflate)functionality and (iii)Suzuki cross-coupling reactions.
700 1 2 _aAnemian, R.
700 1 2 _aCupertino, D.C.
700 1 2 _aMackie, P.R.
700 1 2 _aYeates, S.G.
856 4 0 _uhttps://drive.google.com/file/d/1clSs1xHeycK7NLGSjgmX9_FsP50t7SVa/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942 _2Loc
_cREF1
008 250602s9999 xx |||||s2 |||| ||und|d
999 _c44141
_d44141