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090			_aB-11123
245	1	0	_aModel interpretation of electrochemical impedance spectroscopy and polarization behavior of H2/CO mixture oxidation in polymer electrolyte fuel cells
490	0		_vElectrochimica Acta, 46, p.4397-4405, 2001
520	3		_aA mathematical model is proposed based on electrode kinetics analysis for the oxidation of 2 porcent CO+H2 mixture in polymer electrolyte fuel cells. Successful simulation of the polarization curve and experimental impedance spectra for Pt/C electrode system confirm the validity of the model which shows that the impedance is strongly dependent on electrode potential. With the increase of potential, an inductive behavior will occur. It is believed that the appearance of this inductive pattern can be used as a criterion for the onset of CO oxidation by the coincidence of the potential at which inductive behavior occurs with the ignition potential for CO oxidation. The effects of change of CO oxidation rate constant and CO adsorption equilibrium constant on impedance pattern, as well as on CO surface coverage and Faradaic current are also delineated with the use of the proposed model.
650	1	4	_aFUEL CELL
650	1	4	_aIMPEDANCE
650	1	4	_aMODEL SIMULATION
650	1	4	_aCO OXIDATION
650	1	4	_aELECTROCATALYST
700	1	2	_aWang, X.
700	1	2	_aHsing, I.M.
700	1	2	_aLeng, Y.J.
700	1	2	_aYue, P.
856	4	0	_uhttps://drive.google.com/file/d/1RQC8tHlhNyhETKAxpWcKBPCO8-1lECdq/view?usp=drivesdk _zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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