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090			_aB-11625
245	1	0	_aDevelopment of Supported Bifunctional Electrocatalysts for Unitized Regenerative Fuel Cells
490	0		_vJournal of The ElectroChemical Society, 149, p.1092-1099, 2002
520	3		_aMixed metal catalysts containing Pt, Ir, Ru, Os, and Rh were synthesized on three different conductive oxide supports, Ebonex, which is a mixture of Ti4O7 and other phases, phase-pure microcrystalline Ti4O7 , and Ti0.9Nb0.1O2 , a doped rutile compound. Ebonex-supported catalysts were prepared as arrays and screened combinatorially for activity and stability as bifunctional oxygen reduction/water oxidation catalysts. The highest activity and stability was found in the Pt-Ru-Ir ternary region at compositions near Pt4Ru4Ir1 . X-ray near edge absorption spectra indicated a significant electronic interaction between the catalyst and the support, and a substantial increase in catalyst utilization was observed, even though the support surface areas were relatively low. Both Ebonex and Ti4O7 have short-lived electrochemical stability under conditions of oxygen evolution at 11.6 V vs. RHE in 0.5 M H2SO4 . Current at these supported catalysts gradually decreases, and the decrease is attributed to loss of electronic conductivity. Ebonex and Ti4O7 are also thermally oxidized in air at temperatures above 400°C. In contrast, Ti0.9Nb0.1O2 , which has a nondefective oxygen lattice, is quite resistant to electrochemical and thermal oxidation. Conditioning of Ti0.9Nb0.1O2-supported Pt4Ru4Ir1 at positive potentials had little effect on the activity of the catalyst.
700	1	2	_aChen, G.
700	1	2	_aBare, S.R.
700	1	2	_aMallouk, T.E.
856	4	0	_uhttps://drive.google.com/file/d/1uyRiRiC4SWRTVgH5Kbj7VRv-z9iXWc9c/view?usp=drivesdk _zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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