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245 1 0 _aPEM fuel cell cathode contamination in the presence of cobalt ion (Co2+)
490 0 _vElectrochimica Acta, 55(29), p.5823-5830, 2010
520 3 _aThis paper reports the effects of Co2+ contamination on PEM fuel cell performance as a function of Co2+ concentration and operating temperature. A significant drop in fuel cell voltage occurred when Co2+ was injected into the cathode air stream, and Co2+ contamination became more severe with decreasing temperature. To investigate in detail the mechanism of Co2+ poisoning, AC impedance was monitored before and during Co2+ injection, revealing that both charge transfer and mass transport related processes deteriorated significantly in the presence of Co2+, whereas membrane conductivity decreased to a lesser extent. Surface cyclic voltammetry and contact angle measurements further revealed changes in physical properties, such as active Pt surface area and hydrophilicity, furthering our understanding of the contamination process.
650 1 4 _aPEM FUEL CELLS
650 1 4 _aCOBALT ION CONTAMINATION
650 1 4 _aELECTRODE KINETICS
650 1 4 _aMASS TRANSFER
650 1 4 _aMEMBRANE CONDUCTIVITY
700 1 2 _aLi, H.
700 1 2 _aGazzarri, J.
700 1 2 _aTsay, K.
700 1 2 _aWu, S.
700 1 2 _aWang, H.
700 1 2 _aZhang, J.
700 1 2 _aWessel, S.
700 1 2 _aWessel, S.
700 1 2 _aJoos, N.
700 1 2 _aSchrooten, J.
856 4 0 _uhttps://drive.google.com/file/d/1uBUmxD0Gdqwb7bYDi8_dcV-a8nuoHtP8/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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