000			01402nam a2200169Ia 4500
003			MX-MdCICY
005			20250625140702.0
040			_cCICY
090			_aB-12043
245	1	0	_aElectrons from hydrogen
490	0		_vChem. Commun., 21(23), p.3317-3325, 2009
520	3		_aThe growing need for hydrogen-based fuel cells has driven research into hydrogenase (H2ase)-a natural enzyme that catalyses the extraction of electrons from H2 in water under ambient conditions. Unfortunately, the exact mechanism by which H2ase achieves this feat has remained a matter of some controversy until now, with many mechanisms being inconsistent with experimental data. Recently, however, we have been able to produce a successful catalytic mimic of H2ase that replicates key aspects of it. This paper begins with an overview of the research from many groups that preceded this discovery, followed by a detailed analysis of the key points that set our unique functional model apart-that is to say a proton-like ''hydride'' species, a surprisingly low-valent NiIRuI complex and the key insight that two molecules of H2 are required for electron extraction.
700	1	2	_aOgo, S.
856	4	0	_uhttps://drive.google.com/file/d/1TxkZjSIt0QKTUlvfgnkzYYWP8RW3hiI9/view?usp=drivesdk _zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942			_2Loc _cREF1
008			250602s9999 xx |||||s2 |||| ||und|d
999			_c46255 _d46255