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090 _aB-12197
245 1 0 _aIsothermal Titration Calorimetry: A Powerful Technique To Quantify Interactions in Polymer Hybrid Systems
490 0 _vMacromolecules, 42(19), p.7545-7552, 2009
520 3 _aIsothermal titration calorimetry (ITC)was introduced as a highly sensitive tool to analyze interactions in polymer and material science by their thermodynamic patterns. The thermodynamic parameters ÄH, ÄS, ÄG, KB, and the stoichiometric ratio of the interactions in a complex organic-inorganic hybrid system were determined in a single experiment. In particular, the adsorption behavior of surface-active amphiphilic copolymers, bearing different types of anchor groups (nonionic, zwitterionic, and acidic), with SiO2 nanoparticles in a multicomponent solvent system was investigated. The knowledge of the thermodynamic parameters of the interaction provided, beside its strength, a detailed understanding of its mechanism. Particularly, for the production of the nanocomposites, this knowledge might lead to a more ational and optimized design of these materials.
700 1 2 _aChiad, K.
700 1 2 _aStelzig, S.H.
700 1 2 _aGropeanu, R.
700 1 2 _aWeil, T.
700 1 2 _aKlapper, M.
700 1 2 _aMullen, K.
856 4 0 _uhttps://drive.google.com/file/d/1UKI7A08V_2_qbtGsem6qceqmdLtjZ-T7/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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