000			01195nam a2200205Ia 4500
003			MX-MdCICY
005			20250625140706.0
040			_cCICY
090			_aB-12252
245	1	0	_aThe useful properties of H2O as a ligand of a hydrogenase mimic
490	0		_vDalton Transactions, 39(9), p.2218-2225, 2010
520	3		_aThis paper investigates the required properties of Ru-coordinated ligands of a Ni-Ru based hydrogenase mimic. A series of ligands, including MeCN, pyridine, H2O andOH- were coordinated to Ru, with H2O being the only ligand to promote H2-activation. In addition, a tethered pyridyl moiety was synthesised and found to completely inhibit H2-activation. We conclude, therefore, that H2O is the ideal ligand for this mimic as a result of both its mild basicity and the availability of two lone pairs for simultaneous binding to Ru and H2.
700	1	2	_aZheng, C.
700	1	2	_aKim, K.
700	1	2	_aMatsumoto, K.
700	1	2	_aOgo, S.
856	4	0	_uhttps://drive.google.com/file/d/1pGrId8UuKOXfQZlOS2dNUbFpg-lN6vgV/view?usp=drivesdk _zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942			_2Loc _cREF1
008			250602s9999 xx |||||s2 |||| ||und|d
999			_c46463 _d46463