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245 1 0 _aMechanistic aspects of the thermal degradation of poly(lactic acid)and poly(j?-hydroxybutyric acid)
490 0 _vJournal of Analytical and Applied Pyrolysis, 40-41, p.43-53, 1997
520 3 _aThe thermal degradation of po1yIlactic acid)IPLA)and polyls- hydrnxybutyric acid)(PHB)was investigated by means of several thermoanalytical mctbods, including thcrmogravimetry. d ifferential scaringc alorimetry, pyrolysis-MS and pyrolysis-GC-MST. hese methods supplied information on the ki~ttics of the poIymcr dccompo ion as wxll as on the product composition. The analysis of LA-oligomcrs provided new insights into the stercochemistry of the degradation. The results are discussed in vkw of the known reaction mechanisms for ester pyrolysis. Some of the present results cannot be explained on this basis.
650 1 4 _aBIODEGRADABLE POLYMER
650 1 4 _aPOLYESTER
650 1 4 _aDEGRADATION
650 1 4 _aPOLYLLACTIC ACID)
650 1 4 _aPOLY(P-HYDROXYBUTYRIC ACID)
650 1 4 _aTHERMOANALYSIS; PYROLYSIS
700 1 2 _aKopinke, F.-D.
700 1 2 _aMackenzie, K.
856 4 0 _uhttps://drive.google.com/file/d/1GfOHWjRtECI2skPjNjoAj6dTUxiTh6ZN/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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