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245 1 0 _aDetermination of indole-3-pyruvic acid levels in Arabidopsis thaliana by gas chromatography-selected ion monitoring-mass spectrometry
490 0 _vJournal of Chromatography A, 800(1), p.101-108, 1998
520 3 _aA rapid and simple method is described for the determination of indole-3-pyruvic acid (IPA)levels in Arabidopsis thaliana by gas chromatography-selected ion monitoring-mass spectrometry (GC-SIM-MS). The method includes derivatization of IPA with hydroxylamine in the crude extract, followed by ethyl acetate partitioning, solid-phase extraction with C resin, reversed-phase high-performance liquid chromatography (HPLC), and GC-SIM-MS. Three derivatizing 18 reagents were tested; these were entafluorobenzylhydroxylamine, pentafluorophenylhydrazine, and hydroxylamine. Hydroxylamine proved to be the most useful, as the IPA-oxime was easiest to purify from plant extracts and was the most stable. IPA was quantified in Arabidopsis seedlings ranging in age from 5 to 12 days; levels varied from 4 to 13 ng/ g, peaking at 7-9 days.
650 1 4 _aARABIDOPSIS THALIANA
650 1 4 _aDERIVATIZATION, GC
650 1 4 _aINDOLEPYRUVIC ACID
650 1 4 _aPENTAFLUOROPHENYLHYDRAZINE
650 1 4 _aPENTAFLUOROBENZYLHYDROXYLAMINE
700 1 2 _aTam, Y.Y.
700 1 2 _aNormanly, J.
856 4 0 _uhttps://drive.google.com/file/d/1P0PNyPuM9oprfio3F9dBIN_BNzb2hKd3/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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