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245 1 0 _aMicrostructural and molecular dependence of the work of fracture parameters in semicrystalline and amorphous polymer systems
490 0 _vEuropean Structural integrity, 27, p.213-230, 2000
520 3 _aThe influence of microstructural, morphological and molecular variables on the fracture behavior of polymers and related composites by using the essential work of fracture (EWF)concept has been surveyed in this article. It was postulated that a clear distinction between crack initiation and growth is the essential prerequisite to differentiate between effects of the initial structure and its alteration due to mechanical loading. Strong structural anisotropy in polymers and composites may obstruct the use of the EWF method. It was concluded that the specific essential work of fracture (We)in amorphous polymers is controlled by the molecular entanglement. In semicrystalline polymers We can hardly be correlated with a single parameter of the crystalline or molecular structure. This is owing to a strong interrelation between structural and molecular variables. Results on blends and filled polymeric systems suggest that the essential (resistance to crack initiation)and the non-essential or plastic work (resistance to crack propagation)can hardly be improved simultaneously. This article points out several topics worth of investigations by adopting the EWF method.
650 1 4 _aAMORPHOUS POLYMERS
650 1 4 _aSEMICRYSTALLINE POLYMERS
650 1 4 _aESSENTIAL WORK OF FRACTURE
650 1 4 _aMICROSTRUCTURE
650 1 4 _aMOLECULAR PARAMETERS
650 1 4 _aCRYSTALLINE CHARACTERISTICS
650 1 4 _aENTANGLEMENT NETWORK
650 1 4 _aBLENDS
650 1 4 _aFILLED SYSTEMS
650 1 4 _aCOMPOSITES
700 1 2 _aKarger-Kocsis, J.
856 4 0 _uhttps://drive.google.com/file/d/1Jti7pcmwzkzYLIZQdPTcd0RCk5cQXSj5/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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