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245 1 0 _aCaesalpinone A, a new type of gorgonane sesquiterpenoid containing an unprecedented 1, 15-bridge, from the pods of Caesalpinia spinosa Kuntze.
490 0 _vFitoterapia, 112, p.233-236, 2016
520 3 _aCaesalpinone A (1), a new type of gorgonane sesquiterpenoid containing an unprecedented 1,15-bridge, along with ten known sesquiterpenoids (2 ? 11)were isolated from the pods of Caesalpinia spinosa Kuntze (Tara). The structure of caesalpinone A was elucidated based on its 1D and 2D NMR spectra. The absolute configuration of 1 was assigned by the comparison of the experimental and calculated electronic circular dichroism spectra. Compound 1 was evaluated for the inhibitory activities against five human tumor cell lines. The sesquiterpenoids of isodaucane skeleton and caryolane skeleton were isolated from Caesalpinia genus for the first time. Compounds 5-9 were firstly reported from Tara.
650 1 4 _aTARA
650 1 4 _aCAESALPINIA SPINOSA
650 1 4 _aSESQUITERPENOID
650 1 4 _aCAESALPINONE A
700 1 2 _aMu, W.
700 1 2 _aTang, H.
700 1 2 _aLi, Y.
700 1 2 _aHe, D.
700 1 2 _aMa, R.
700 1 2 _aWang, L.
856 4 0 _uhttps://drive.google.com/file/d/1PQDm8wLsbWZPn3yFMr7vRNf5MEolcnrd/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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