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245	1	0	_aCrystallization and homogeneous nucleation kinetics of poly (?-caprolactone)(PCL)with different molar masses.
490	0		_vMacromolecules, 45(9), p.3816-3828., 2012
520	3		_aThe crystallization and nucleation kinetics of poly(?-caprolactones)(PCL)with molar masses between 1.4 and 6.1 kDa and negligible number of heterogeneous nuclei has been investigated by differential fast scanning calorimetry (DFSC)applying scanning rates up to 100?000 K/s. The samples were synthesized by ring-opening polymerization and chemically characterized by NMR spectroscopy, size exclusion chromatography (SEC), and multiangle laser light scattering (MALLS). For the smallest molar mass the chain length is comparable with the crystal thickness measured with small-angle X-ray scattering (SAXS), and extended chain like crystals may be formed. Because of the molar mass distribution (PDI ? 2), these crystals have a significant noncrystalline interface yielding nearly the same crystallinity for all molar masses. The critical cooling rate to obtain amorphous samples is below 1000 K/s and only for the lowest molar mass increased to 2000 K/s. The same trend holds for the about 1 order of magnitude higher critical heating rate to keep the samples amorphous on heating and for the analysis of isothermal nucleation and crystallization kinetics at 202 K. The samples which were shown not to contain heterogeneous nuclei active at a heating rate of >18?000 K/s were used for a study of the nucleation activity of ordered structures formed on annealing at low temperature. The analysis of the change of the thus-produced amorphous polymer samples on annealing from 202 to 272 K for times varying by a factor of more than 108 (0.1 ms to 8.3 h)revealed new details about the ordering processes (nucleation, poor crystal formation, crystallization, cold crystallization, and crystal perfection)and the accompanying changes in glass transition of the remaining amorphous phase (formation of rigid amorphous phases, RAF).
650	1	4	_aPOLY(?-CAPROLACTONE)
700	1	2	_aWurm, A.
700	1	2	_aZhuravlev, E.
700	1	2	_aEckstein, K.
700	1	2	_aJehnichen, D.
700	1	2	_aPospiech, D.
700	1	2	_aAndrosch, R.
700	1	2	_aSchick, C.
856	4	0	_uhttps://drive.google.com/file/d/1s44_PSMZ-2auxOAIWH9InSjsbcsHGaoy/view?usp=drivesdk _zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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