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090 _aB-18986
245 1 0 _aPreparation of crystalline starch nanoparticles using cold acidhydrolysis and ultrasonication
490 0 _vCarbohydrate Polymers, 98(1), p.295-301, 2013
520 3 _aWaxy maize starch in an aqueous sulfuric acid solution (3.16 M, 14.7 percent solids)was hydrolyzed for 2-6 days, either isothermally at 40 °C or 4 °C, or at cycled temperatures of 4 and 40 °C (1 day each). The starch hydrolyzates were recovered as precipitates after centrifuging the dispersion (10,000 rpm, 10 min). The yield of starch hydrolyzates depended on the hydrolysis temperature and time, which varied from 6.8 percent to 78 percent. The starch hydrolyzed at 40 °C or 4/40 °C exhibited increased crystallinity determined by X-ray diffraction analysis, but melted in broader temperature range (from 60 °C to 110 °C). However, the starch hydrolyzed at 4 °C displayed the crystallinity and melting endotherm similar to those of native starch. The starch hydrolyzates recovered by centrifugation were re-dispersed in water (15 percent solids), and the dispersion was treated by an ultrasonic treatment (60 percent amplitude, 3min). The ultrasonication effectively fragmented the starch hydrolyzates to nanoparticles. The hydrolyzates obtained after 6 days of hydrolysis were more resistant to the ultrasonication than those after 2 or 4 days, regardless of hydrolysis temperatures. The starch nanoparticles could be prepared with high yield (78 percent)and crystallinity by 4 °C hydrolysis for 6 days followed by ultrasonication. Scanning electron microscopy revealed that the starch nanoparticles had globular shapes with diameters ranging from 50 to 90 nm.
650 1 4 _aACID HYDROLYSIS
650 1 4 _aNANOCRYSTALS
650 1 4 _aNANOPARTICLES
650 1 4 _aSTARCH
650 1 4 _aULTRASONICATION
700 1 2 _aKim, H. Y.
700 1 2 _aPark, D. J.
700 1 2 _aKim, J. Y.
700 1 2 _aLim, S. T.
856 4 0 _uhttps://drive.google.com/file/d/1uxHErod-7W9bFOEDC5SGIJf7YhbbOKM5/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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