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090 _aB-19758
245 1 0 _aMetal-free, low-cost, and high-performance membraneless ethanol fuel cell
490 0 _vJournal of Power Sources, 551, p.232164, 2022
520 3 _aRenewable energy conversion from biomass in fuel cells can mitigate the imbalance between the carbon sequestration and sustainable energy demands. Ethanol biofuel cells based on NAD-dependent alcohol dehydrogenase (ADH)as catalyst are suitable alternatives; however, metal-free electrodes are still not effective for achieving a satisfactory power density. We report a membraneless and metal-free ethanol-O2 biofuel cell that is entirely composed of organic and biological molecules. The biofuel cell is based on a redox-active quinone-based catalyst produced by one-pot synthesis that operates efficiently with high power density (264 mW m?2), at mild conditions of pH and room temperature. The cost of this biofuel cell is more than 2.5-fold lower than that of a conventional system with a Pt-based electrocatalyst, potentially enabling cost-effective production of renewable electricity.
650 1 4 _aETHANOL-O2 FUEL CELL
650 1 4 _aMETAL-FREE CATALYST
650 1 4 _aNAD-DEPENDENT ALCOHOL DEHYDROGENASE
650 1 4 _aBIOELECTROCATALYSIS
650 1 4 _aIN SITU EPR SPECTROSCOPY
700 1 2 _aAli, M. A.
700 1 2 _aSedenho, G. C.
700 1 2 _aPacheco, J. C.
700 1 2 _aIost, R. M.
700 1 2 _aRahman, A.
700 1 2 _aHassan, A.
700 1 2 _aCrespilho, F. N.
856 4 0 _uhttps://drive.google.com/file/d/1gIdJasHrA4Eugli0Wq4_-Y4s_ldnQMTr/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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