000			01955nam a2200277Ia 4500
003			MX-MdCICY
005			20250625162452.0
040			_cCICY
090			_aB-20606
245	1	0	_aUnraveling the Asymmetric O- O Radical Coupling Mechanism on Ru- O- Co for Enhanced Acidic Water Oxidation
490	0		_vSmall, 19(45), p.2304889, 2023
520	3		_aHeterogeneous oxides with multiple interfaces provide significant advantages in electrocatalytic activity and stability. However, controlling the local structure of these oxides is challenging. In this work, unique heterojunctions are demonstrated based on two oxide types, which are formed via pyrolysis of a ruthenocene metal-organic framework (Ru-MOF)at specific temperatures. The resulted Ru-MOF-400 exhibits excellent electrocatalytic activity, with an overpotential of 190 mV at a current density of 10 mA cm-2 in 0.1 m HClO4 , and a mass activity of 2557 A gRu -1 , three orders of magnitude higher than commercial RuO2 . The Ru?O?Co bond formed by the incorporation of Co into the rutile lattice of RuO2 inhibits the disolution of Ru. Operando electrochemical investigations and density functional theory results reveal that the Ru-MOF-400 undergo asymmetric dual-active site oxide path mechanism during the acidic oxygen evolution reaction process, which is predominantly mediated by the asymmetric Ru?Co dual active site present at the interfaces between Co3 O4 and CoRuOx
650	1	4	_aACIDIC OXYGEN EVOLUTION REACTION
650	1	4	_aELECTROCATALYSTS
650	1	4	_aHETEROGENEOUS OXIDES
700	1	2	_aLiang, J.
700	1	2	_aGao, X.
700	1	2	_aXu, K.
700	1	2	_aLu, J.
700	1	2	_aLiu, D.
700	1	2	_aZhao, Z.
700	1	2	_aLiu, J.
856	4	0	_uhttps://drive.google.com/file/d/17vka6kazEmnsG2zx72qrmftocHxsfg8A/view?usp=drivesdk _zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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