000 02929nam a2200301Ia 4500
003 MX-MdCICY
005 20250625162452.0
040 _cCICY
090 _aB-20621
245 1 0 _aMicro-nano scale pore structure and fractal dimension of ultra-high performance cementitious composites modified with nanofillers
490 0 _vCement and Concrete Composites, 141, p.105129, 2023
520 3 _aThe development of ultra-high performance cementitious composite (UHPCC)represents a significant advancement in the field of concrete science and technology, but insufficient hydration and high autogenous shrinkage relatively increase the pores inside UHPCC, in turn, affecting the macro-performance of UHPCC. This paper, initially, optimized the pore structure of UHPCC using different types and dimensions of nanofillers. Subsequently, the pore structure characteristics of nano-modified UHPCC were investigated by the mercury intrusion porosimeter method and fractal theory. Finally, the fluid permeability of nano-modified UHPCC was estimated by applying the Katz-Thompson equation. Experimental results showed that all incorporated nanofillers can refine the pore structure of UHPCC, but nanofillers with different types and dimensions have various effects on the pore structure of UHPCC. Specifically, CNTs, especially the thin-short one, can significantly reduce the porosity of UHPCC, whereas nanoparticles, especially nano-SiO2, are more conducive to refine the pore size. Among all nanofillers, nano-SiO2 has the most obvious effect on pore structure, reducing the porosity, specific pore volume and most probable pore radius of UHPCC by 31.9 percent, 35.1 percent and 40.9 percent, respectively. Additionally, the pore size distribution of nano-modified UHPCC ranges from 10?1nm-105nm, and the gel pores and fine capillary pores in the range of 3-50 nm account for more than 70 percent of the total pore content, confirming nanofillers incorporation can effectively weaken pore connectivity and induce pore distribution to concentrate at nanoscale. Fractal results indicated the provision of nanofillers reduces the structural heterogeneity of gel pores and fine capillary pores, and induces homogenization and densification of UHPCC matrix, in turn, decreasing the UHPCC fluid permeability by 15.7 percent-79.2 percent.
650 1 4 _aULTRA-HIGH PERFORMANCE CEMENTITIOUS COMPOSITES
650 1 4 _aNANOFILLER MODIFYING
650 1 4 _aPORE STRUCTURE
650 1 4 _aFLUID PERMEABILITY
650 1 4 _aFRACTAL THEORY
700 1 2 _aWang, J.
700 1 2 _aWang, X.
700 1 2 _aDing, S.
700 1 2 _aAshour, A.
700 1 2 _aYu, F.
700 1 2 _aLv, X.
700 1 2 _aHan, B.
856 4 0 _uhttps://drive.google.com/file/d/1o2qAx2OkVuWIxOIRVmbonpiSs7lJ7siv/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942 _2Loc
_cREF1
008 250602s9999 xx |||||s2 |||| ||und|d
999 _c54707
_d54707