000			02085nam a2200241Ia 4500
003			MX-MdCICY
005			20250625162454.0
040			_cCICY
090			_aB-20743
245	1	0	_aSurface molecular characterisation of different epoxy resin composites subjected to UV accelerated degradation using XPS and ToF-SIMS
490	0		_vPolymer Degradation and Stability, 94(4), p.651-658, 2009
520	3		_aEpoxy resin composites reinforced with E-glass (E), 3D glass (3D)and carbon fibre (CF)were subjected to an intense UV and high temperature accelerated degradation environment. X-ray photoelectron spectroscopy (XPS)and time-of-flight secondary ion mass spectrometry (ToF-SIMS)were used to provide a molecular characterisation of the surface of the degraded composites. The response at the surface of the epoxy resin composites to oxidative degradation is influenced by the composite reinforcement type and characteristics. XPS results indicate that 3D resin composites exhibit more surface oxidation as a result of the accelerated degradation in comparison with E and CF composites. Principal components analysis (PCA)of the ToF-SIMS positive ion spectra showed that E and 3D resin composites suffered chain scission while CF composites suffered chain scission and cross-linking reactions as a result of the intense UV exposure. The extent of the surface oxidation, cross-linking/condensation reaction and loss of low molecular weight (lower than C4Hx)aliphatic hydrocarbons may be indicated using PCA of both the ToF-SIMS positive and negative ion spectra. PCA also provides insight for proposing epoxy resin chain scission and oxidation reaction mechanisms.
650	1	4	_aTOF-SIMS
650	1	4	_aXPS
650	1	4	_aACCELERATED DEGRADATION
650	1	4	_aEPOXY RESIN
650	1	4	_aUV
700	1	2	_aAwaja, F.
700	1	2	_aPigram, P. J.
856	4	0	_uhttps://drive.google.com/file/d/1jL9lpOomJHJpoJCcB-6aOR_byBEGABeg/view?usp=drivesdk _zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942			_2Loc _cREF1
008			250602s9999 xx |||||s2 |||| ||und|d
999			_c54824 _d54824