000 01968nam a2200301Ia 4500
003 MX-MdCICY
005 20250625162458.0
040 _cCICY
090 _aB-20972
245 1 0 _aBiomass derived nitrogen and sulfur co-doped porous carbons for efficient CO2 adsorption
490 0 _vSeparation and Purification Technology, 281, p.119899, 2022
520 3 _aIn this work, novel nitrogen and sulfur co-doped porous carbons were synthesized by thiourea modification of carbonized hazelnut shell, then followed by KOH activation. In current preparation protocol, thiourea acted as both N and S agent, thereby, nitrogen and sulfur were simultaneously doped into the carbon skeleton by a single-step reaction. After KOH activation, the resultant sorbents hold advanced porosity and a certain amount of N and S contents. This series of sorbents possess the highest CO2 uptake of 4.30 and 6.44 mmol g?1 at 1 bar, 25 °C and 0 °C, respectively. Comprehensive investigations found that the joint effects of narrow microporostiy, N and S content govern the CO2 uptake of these adsorbents. Moreover, these adsorbents display various exceptional CO2 adsorption performances such as excellent reversibility, fast CO2 adsorption kinetics, moderate heat of adsorption, good CO2/N2 selectivity and high dynamic CO2 capture capacity. Therefore, these hazelnut shell derived N, S co-doped carbons are promising in actual CO2 capture.
650 1 4 _aCO2 ADSORPTION
650 1 4 _aN
650 1 4 _aS CO-DOPED
650 1 4 _aPOROUS CARBÓN
650 1 4 _aTHIOUREA MODIFICATION
650 1 4 _aBIOMASS
700 1 2 _aMa, C.
700 1 2 _aLu, T.
700 1 2 _aShao, J.
700 1 2 _aHuang, J.
700 1 2 _aHu, X.
700 1 2 _aWang, L.
856 4 0 _uhttps://drive.google.com/file/d/17uaT5fDfv9QXCzIACs7imaHZHqVf9GOr/view?usp=drivesdk
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942 _2Loc
_cREF1
008 250602s9999 xx |||||s2 |||| ||und|d
999 _c55051
_d55051