000 02651nam a2200241Ia 4500
003 MX-MdCICY
005 20250625162500.0
040 _cCICY
090 _aB-21080
245 1 0 _aLiquid metal batteries for future energy storage
490 0 _vEnergy & Environmental Science, 14(8), p.4177-4202, 2021
520 3 _aThe search for alternatives to traditional Li-ion batteries is a continuous quest for the chemistry and materials science communities. One representative group is the family of rechargeable liquid metal batteries, which were initially exploited with a view to implementing intermittent energy sources due to their specific benefits including their ultrafast electrode charge-transfer kinetics and their ability to resist microstructural electrode degradation. Although conventional liquid metal batteries require high temperatures to liquify electrodes, and maintain the high conductivity of molten salt electrolytes, the degrees of electrochemical irreversibility induced by their corrosive active components emerged as a drawback. In addition, safety issues caused by the complexity of parasitic chemical reactivities at high temperatures further complicated their practical applications. To address these challenges, new paradigms for liquid metal batteries operated at room or intermediate temperatures are explored to circumvent the thermal management problems, corrosive reactions, and challenges related to hermetic sealing, by applying alternative electrodes, manipulating the underlying electrochemical behavior via electrolyte design concepts, and engineering the electrode-electrolyte interfaces, thereby enabling both conventional and completely new functionalities. This report briefly summarizes previous research on liquid metal batteries and, in particular, highlights our fresh understanding of the electrochemistry of liquid metal batteries that have arisen from researchers' efforts, along with discovered hurdles that have been realized in reformulated cells. Finally, the feasibility of new liquid metal batteries is discussed along with their distinct chemistries and performance characteristics to answer the question of how liquid metals can be accessible for next-generation battery systems.
700 1 2 _aZhang, S.
700 1 2 _aLiu, Y.
700 1 2 _aFan, Q.
700 1 2 _aZhang, C.
700 1 2 _aZhou, T.
700 1 2 _aKalantar-Zadeh, K.
700 1 2 _aGuo, Z.
856 4 0 _uhttps://drive.google.com/open?id=18VzsKnt3WbeEbVnG9uWKfZ8ELUqdOXc6&usp=drive_copy
_zPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942 _2Loc
_cREF1
008 250602s9999 xx |||||s2 |||| ||und|d
999 _c55158
_d55158