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245 1 0 _aSuperhydrophobic starch-based cryogels modified with silylated magnetic nanoparticles for oil spill cleanup
490 0 _aJournal of Cleaner Production. 363, 132492, 2022, DOI: 10.1016/j.jclepro.2022.132492
520 3 _aSuperhydrophobic smart adsorbents have attracted wide attention for the cleanup of oil spill that endangers the aquatic ecosystem. Herein, a super-water-repellent coating (HOS/Fe3O4) was achieved through hydrolytic condensation of hexadecyltrimethoxysilane and tetraethyl orthosilicate in the presence of Fe3O4 nanoparticles. The coating was then introduced onto the surface of starch cryogel (SC) by spray-coating technique to fabricate the superhydrophobic and magnetic starch-based adsorbent (HOS/Fe3O4@SC). The surface chemical composition and hierarchical micro/nanostructures that contribute to the high water contact angle (>151°) and low sliding angle (<5°) of the as-obtained material were characterized in detail. The HOS/Fe3O4@SC exhibited excellent water repellent, self-cleaning, and anti-fouling properties. The structural support and stable chemical bonding endow the material with good mechanical and chemical durability. The HOS/Fe3O4@SC also possessed reasonable adsorption capacities to various organic solvents, and its oil absorption kinetics was also comprehensively studied. The HOS/Fe3O4@SC can be applied for heavy oil absorption underwater and magnetically guided oil slick cleaning. This novel starch-based absorbent exhibits promising application in tackling oil contamination in complex environments. © 2022 Elsevier Ltd
650 1 4 _aADSORBENT
650 1 4 _aFE3O4
650 1 4 _aOIL SPILL
650 1 4 _aSTARCH-BASED CRYOGEL
650 1 4 _aSUPERHYDROPHOBIC
650 1 4 _aSURFACE COATING
700 1 2 _aWang F.
700 1 2 _aMa R.
700 1 2 _aZhan J.
700 1 2 _aWang T.
700 1 2 _aTian Y.
856 4 0 _uhttps://drive.google.com/file/d/1S3jYBtUEZQvfh0gwiLLzuoL99q3i4Eb5/view?usp=drivesdk
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