000			03469nam a22004575i 4500
001			978-0-387-25972-7
003			DE-He213
005			20250710083935.0
007			cr nn 008mamaa
008			110416s2005 xxu| s |||| 0|eng d
020			_a9780387259727 _a99780387259727
024	7		_a10.1007/b136380 _2doi
082	0	4	_a541.395 _223
100	1		_aVannice, M. Albert. _eauthor.
245	1	0	_aKinetics of Catalytic Reactions _h[recurso electrónico] / _cby M. Albert Vannice.
264		1	_aBoston, MA : _bSpringer US, _c2005.
300			_bonline resource.
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_arecurso en línea _bcr _2rdacarrier
347			_atext file _bPDF _2rda
505	0		_aDefinitions and Concepts -- Catalyst Characterization -- Acquisition and Evaluation of Reaction Rate Data -- Adsorption and Desorption Processes -- Kinetic Data Analysis and Evaluation of Model Parameters for Uniform (Ideal) Surfaces -- Modeling Reactions on Uniform (Ideal) Surfaces -- Modeling Reactions on Nonuniform (Nonideal) Surfaces -- Kinetics of Enzyme-Catalyzed Reactions.
520			_aThis textbook contains all the information needed for graduate students or industrial researchers to design kinetic experiments involving heterogeneous catalysts, to characterize these catalysts, to acquire valid rate data, to verify the absence of mass (and heat) transfer limitations, to propose reaction models, to derive rate expressions based on these models and, finally, to assess the consistency of these rate equations. Langmuir, Freundlich, and Temkin isotherms are derived and the former are used in Langmuir-Hinshelwood (and Hougen-Watson) models, as well as reaction sequences without a rate-determining step, to obtain rate expressions on uniform surfaces. In addition, rate equations based on non-uniform (Temkin-type) surfaces are examined as an alternative approach. The most recent technique to calculate heats of adsorption and activation barriers on metal surfaces, the BOC-MP approach, is discussed in detail. Methods to measure metal surface areas and crystallite sizes using x-ray diffraction, transmission electron microscopy and various chemisorption techniques are discussed. Different experimental techniques to determine the influence of mass transfer limitations, especially within the pores of a catalyst, are reviewed in detail, with a particular emphasis on liquid-phase reactions. Many illustrations of these and other topics are provided along with numerous problems and a Solutions Manual for instructors. This book will be applicable to any graduate course in chemical engineering, chemistry or materials science that involves kinetics of catalytic reactions, including those catalyzed by enzymes.
650		0	_aCHEMISTRY.
650		0	_aCHEMISTRY, INORGANIC.
650		0	_aCHEMISTRY, PHYSICAL ORGANIC.
650		0	_aCHEMICAL ENGINEERING.
650		0	_aCATALYSIS.
650	1	4	_aCHEMISTRY.
650	2	4	_aCATALYSIS.
650	2	4	_aINORGANIC CHEMISTRY.
650	2	4	_aPHYSICAL CHEMISTRY.
650	2	4	_aINDUSTRIAL CHEMISTRY/CHEMICAL ENGINEERING.
710	2		_aSpringerLink (Online service)
773	0		_tSpringer eBooks
776	0	8	_iPrinted edition: _z9780387246499
856	4	0	_uhttp://dx.doi.org/10.1007/b136380 _zVer el texto completo en las instalaciones del CICY
912			_aZDB-2-CMS
942			_2ddc _cER
999			_c56511 _d56511